webmin and centos will usually default to bind-chroot installation and webmin will have the chroot paths set for named.conf
for some reason, in my centos 6.2 setup there was a folder permission issue which prevented the pid file from being created.
chmod 770 /var/named/chroot/etc/
and then it started
one more thing to pay attention to. if you setup virtualmin and use the local named for your domains, then you have to set 127.0.0.1 as the first entry in /etc/resolv.conf